PTFE (polytetrafluoroethylene) is a fluoropolymer used for seals, gaskets, bearings, linings and insulation where low friction, chemical resistance or a wide temperature range is needed. Unfilled PTFE has a density of 2.13 to 2.19 g/cm3, a maximum continuous service temperature of 260 C and a dynamic friction coefficient against steel of 0.06 to 0.08. It is a soft material: its tensile strength of 15 to 35 MPa is a small fraction of any engineering metal.
Properties of unfilled PTFE
Values are for virgin, unfilled PTFE at room temperature unless stated. Where the published datasheets agree, the table gives the agreed figure or the band they overlap on. Where they do not, it gives the spread of what is published and says so.
| Property |
Unfilled PTFE |
Agreement |
| Density | 2.13 to 2.19 g/cm3 | Sources agree |
| Tensile strength | 15 to 35 MPa | Sources agree |
| Elongation at break | 150 to 350 % | Sources agree |
| Hardness | 55 to 64 Shore D | Sources agree |
| Coefficient of friction, dynamic against steel | 0.06 to 0.08 | Sources agree |
| Maximum continuous service temperature | 260 C | Sources agree |
| Minimum service temperature | -260 to -200 C | Published figures vary (2 sources) |
| Melting point | 327 C | Sources agree |
| Thermal expansion, about 23 to 100 C | 130 x 10-6 per K | Sources agree |
| Thermal conductivity | 0.2 to 0.34 W/m.K | Published figures vary (5 sources) |
| Dielectric strength, thin film in air | 60 to 80 kV/mm | Sources agree |
| Dielectric constant | 2.1 | Sources agree |
| Water absorption, 24 hours | 0 to 0.05 % | Published figures vary (4 sources) |
What the numbers mean in practice
The temperature range is the main reason PTFE is chosen. It keeps its properties from cryogenic temperatures up to 260 C and does not melt until 327 C. Published minimum temperatures differ, -260 to -200 C depending on the source, because the lower limit is set by how brittle the part is allowed to become, not by a change in the polymer.
The friction coefficient is among the lowest of any solid, which is why PTFE is used for dry bearings, slide pads and seal faces. The trade-off is strength and creep. PTFE deforms slowly under a steady load, so a PTFE gasket or seat relaxes after tightening and may need retorquing, and a PTFE bearing has to be sized for a low contact pressure.
Thermal expansion is high, 130 x 10-6 per K, many times that of steel. A PTFE part that fits at room temperature will be tight or loose at working temperature, so clearances have to allow for it.
PTFE is an electrical insulator with a low dielectric constant of 2.1, which stays almost constant across frequency. That, with near zero water absorption, is why it is used for cable insulation and high frequency components.
Filled PTFE
Glass, carbon, bronze and graphite fillers are added to reduce creep and wear and to raise stiffness. Filled grades have different values from the table above, in some cases very different, so use the supplier's datasheet for the specific compound. This page covers unfilled material only.
PTFE for seals and O-rings
Solid PTFE has almost no elastic recovery, so it does not behave like a rubber O-ring. It is used as back-up rings, as spring-energised or encapsulated seals, and as gaskets and valve seats. Where a chemically resistant seal has to be elastic, a perfluoroelastomer is the usual answer: see Kalrez and Chemraz FFKM O-rings and O-ring material selection.
References
- BS EN ISO 13000 - Plastics, PTFE semi-finished products
- ASTM D4894 - PTFE granular moulding and ram extrusion materials
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